Syntheses of N‐diazinyl thiocarboxamides and of thiazolodiazines. Metalation studies. Diazines XXXIII
Identifieur interne : 001731 ( Main/Exploration ); précédent : 001730; suivant : 001732Syntheses of N‐diazinyl thiocarboxamides and of thiazolodiazines. Metalation studies. Diazines XXXIII
Auteurs : Corinne Fruit [France] ; Alain Turck [France] ; Nelly Plé [France] ; Guy Quéguiner [France]Source :
- Journal of Heterocyclic Chemistry [ 0022-152X ] ; 2002-09.
English descriptors
- KwdEn :
- Anal, Calcd, Chem, Deuteriochloroform, Dichloromethane, Dichloromethane solution, Electrophile, Eluent, Ethyl acetate, Heterocyclic chem, Isolable product, Lithium, Ltmp, Magnesium sulfate, Metalating, Metalating agent, Metalation, Methyl iodide, Methyl phenyldithiocarboxylate, Mmol, Petroleum ether, Phosphorous pentasulfide, Reagent, Room temperature, Sulfur atom, Tetrahydrofuran, Thiazolodiazines, Thiocarboxamides, Turck.
- Teeft :
- Anal, Calcd, Chem, Deuteriochloroform, Dichloromethane, Dichloromethane solution, Electrophile, Eluent, Ethyl acetate, Heterocyclic chem, Isolable product, Lithium, Ltmp, Magnesium sulfate, Metalating, Metalating agent, Metalation, Methyl iodide, Methyl phenyldithiocarboxylate, Mmol, Petroleum ether, Phosphorous pentasulfide, Reagent, Room temperature, Sulfur atom, Tetrahydrofuran, Thiazolodiazines, Thiocarboxamides, Turck.
Abstract
Two thiazolodiazines were prepared from the corresponding N‐diazinylcarboxamides by use of Lawesson's reagent. Two N‐diazinylthiocarboxamides were obtained from amino derivatives by reaction with methyl phenyldithiocarboxylate. The metalation of these four compounds was studied and the thiazolodiazines could be functionalized.
Url:
DOI: 10.1002/jhet.5570390536
Affiliations:
Links toward previous steps (curation, corpus...)
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- to stream Istex, to step Curation: 000305
- to stream Istex, to step Checkpoint: 000460
- to stream Main, to step Merge: 001996
- to stream Main, to step Curation: 001731
Le document en format XML
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<front><div type="abstract" xml:lang="en">Two thiazolodiazines were prepared from the corresponding N‐diazinylcarboxamides by use of Lawesson's reagent. Two N‐diazinylthiocarboxamides were obtained from amino derivatives by reaction with methyl phenyldithiocarboxylate. The metalation of these four compounds was studied and the thiazolodiazines could be functionalized.</div>
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